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[GMP相关] EDI常见问题

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药士
发表于 2016-12-15 23:39:30 | 显示全部楼层 |阅读模式

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本帖最后由 beiwei5du 于 2016-12-15 23:40 编辑

Frequently Asked Questions                                                                        
                                
                        
                                       
This section will address some questions commonly asked.  If you do not find the answer to your question, please contact  techcenter@cediuniversity.com.
Q: What is Electrodeionization?
A: Electrodeionization is the chemical-free process in which ions are removed from water via electric potential. Ions are forced from the dilute compartments into adjacent reject compartments resulting in high purity water. This electric potential also constantly regenerates the resin in the module rather than conventional ion exchange units which use acid and caustic to regenerate. EDI is currently designed to polish RO permeate (product).
Q: What are the advantages of using EDI rather than conventional mixed bed deionization?
A: EDI is a continuous process and the only thing you need is electricity to regenerate the resin. Conventional ion exchange is a batch process which requires large vessels filled with resin, acid/caustic injection systems, a neutralization waste system and all associated controls. Such chemicals can be costly, hazardous and typically requires more space than the equivalent EDI system.
Q: Can EDI Systems handle small amounts of free chlorine the same way TFC RO membranes can?
A: Actually, neither can tolerate free chlorine. We have seen damage to both RO membranes and EDI Modules at concentrations as low as 0.05 ppm. However, it is possible for EDI Module damage to be seen before the RO membranes show signs of chlorine attack.
Q: Why are the limits for hardness concentration in the EDI system feed water so low?
A: Scale can form inside the EDI Module concentrate compartments even at relatively low hardness concentrations because of the high recovery of the EDI System and pH shifts which can occur in the module.
Q: Why are there limits on the iron and manganese concentrations going into EDI system? Aren't these materials removed by ion exchange?
A: Iron and manganese can be removed by ion exchange but can cause problems in a EDI Module because they are held tightly by the resins and may oxidize and precipitate in the resin before they can be transferred out to the waste stream.
Q: Why must the feed water temperature be at least 41oF (5oC)? Why is the minimum temperature specification even higher when silica removal is important?
A: The electrical resistance of the EDI system increases with decreasing temperature. The power supplies for EDI systems are sized to compensate for this down to a temperature of 41oF (5oC) below that temperature the performance may decline due to DC voltage limitations.
Q: Can EDI Systems be installed outdoors?
A: EDI systems must be sheltered from direct sunlight. Also, if ambient temperatures routinely exceed 95oF (35oC) or go below 41oF (5oC) it is not recommended to install the EDI system outdoors. In any outdoor installation, special control enclosures are required to protect the EDI system from humidity, excessive temperatures and other natural elements (rain, sleet, snow).
Q: Is it OK to install a EDI system in the distribution loop instead of directly after the RO system?
A: Yes, EDI systems can be and have been installed in a distribution loop. However, the reject stream from the EDI system results in 5% of the loop water being continuously drawn out of the loop. This water can be returned ahead of the system for re-use.
Q: Do EDI Systems have a difficult time removing CO2? Why is the CO2 concentration in the EDI feed water so important?
A: CO2 is removed by EDI systems just as dissolved salts such as sodium chloride are. We call particular attention to the feed water CO2 concentration for two main reasons. The first is that CO2 is weakly ionized in water so its concentration is not measured by conductivity measurements. The second reason is that CO2 is often a significant portion of the load on the EDI System because it is not removed by RO systems.
Q: Can I raise the pH of the  EDI system feed water with caustic to eliminate the CO2?
A: pH adjustment has to be done in the feed to the RO system to improve the EDI performance. Raising the pH of RO permeate will not improve the EDI product water quality. Raising the pH before the RO allows the RO to remove the CO2 as bicarbonate, preventing the CO2 from reaching the EDI.
Q: How much back pressure can a EDI module handle?
A: The back pressure on the EDI module is limited only by the requirement that the inlet pressure be 100 psi or below. So, if the EDI System is operating at a flow rate which results in a 20 psi pressure drop the maximum back pressure would be 80 psi.
Q: How long does the EDI System take to come back up to quality after being in stand-by?
A: Typically a EDI System will return to quality within a few seconds of starting up from stand-by. It takes much longer however, to come back to quality after cleaning or sanitization, several hours or overnight.
Q: What is the recommended frequency of sanitization for EDI Systems?
A: The frequency of sanitization varies greatly with the customer's bacteria specifications and the system design. Some systems are never sanitized but typical frequencies for systems producing Purified Water range from weekly to quarterly.
Q: What is the typical life of the EDI resin and membrane cell packs?
A: Three to five years is considered a normal life for the cell packs. The useful life obtained at any given site will be a function of the raw water quality, the pretreatment design and how well the system is monitored and maintained.  

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药士
发表于 2016-12-15 23:56:59 | 显示全部楼层
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药师
发表于 2016-12-16 07:46:23 | 显示全部楼层
学习一下啦,谢谢提供分享。
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药生
发表于 2016-12-16 08:05:33 | 显示全部楼层
请出示中文版。谢谢楼主
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药徒
发表于 2016-12-16 09:16:32 | 显示全部楼层
本节将讨论常见问题的一些问题。如果您没有找到您的问题的答案,请联系techcenter@cediuniversity.com
问:什么是电脱离子?
A:电去离子是通过电势从水中去除离子的无化学过程。迫使离子从稀的隔室进入相邻的废料隔室,产生高纯度的水。该电势也不断地再生模块中的树脂,而不是使用酸和苛性碱再生的常规离子交换单元。 EDI目前设计用于抛光RO渗透物(产品)。
问:使用EDI而不是常规混合床去离子的优点是什么?
答:EDI是一个连续的过程,你唯一需要的是再生树脂的电。常规的离子交换是间歇法,其需要填充树脂,酸/苛性碱注射系统,中和废物系统和所有相关控制的大容器。这种化学品可能是昂贵的,危险的,并且通常比等效的EDI系统需要更多的空间。
问:EDI系统能否以同样的方式处理少量的游离氯,TFC RO膜可以?
A:其实,两者都不能容忍游离氯。我们已经看到在低至0.05ppm的浓度下对RO膜和EDI模块的损伤。然而,在RO膜显示氯攻击的迹象之前可能看到EDI模块损坏。
问:为什么EDI系统中的硬度浓度限制水这么低?
A:由于EDI系统的高回收率和模块中可能发生的pH变化,即使在相对低的硬度浓度下,也可以在EDI Module浓缩室内形成水垢。
问:为什么进入EDI系统的铁和锰浓度有限制?这些材料是否通过离子交换去除?
A:铁和锰可以通过离子交换除去,但是在EDI模块中可能引起问题,因为它们被树脂紧密地保持并且可以在树脂中氧化和沉淀,然后它们可以转移到废物流中。
问:为什么给水温度必须至少为41°F(5℃)?为什么当硅石去除很重要时,最低温度规格更高?
A:EDI系统的电阻随着温度的降低而增加。用于EDI系统的电源的尺寸可以补偿这一温度低于该温度41°F(5℃),性能可能由于直流电压限制而下降。
问:EDI系统可以安装在户外吗?
答:EDI系统必须避免阳光直射。此外,如果环境温度通常超过95oF(35oC)或低于41oF(5oC),建议不要在室外安装EDI系统。在任何户外安装中,需要特殊的控制箱,以保护EDI系统免受潮湿,过高的温度和其他自然因素(雨,雨夹雪,雪)。
问:是否可以在分发环路中安装EDI系统,而不是直接在RO系统之后?
答:是的,EDI系统可以并已经安装在分发循环中。然而,来自EDI系统的废物流导致5%的回路水被连续地从回路中抽出。这种水可以在系统之前返回以便重复使用。
问:EDI系统难以清除二氧化碳?为什么EDI给水中的CO2浓度如此重要?
A:CO 2通过EDI系统除去,正如溶解的盐例如氯化钠。我们特别注意给水CO2浓度有两个主要原因。第一个是CO 2在水中弱电离,因此其浓度不通过电导率测量来测量。第二个原因是,CO2通常是EDI系统负载的重要部分,因为它不会被RO系统移除。
问:我可以用苛性碱提高EDI系统给水的pH值以消除CO2吗?
A:必须在RO系统的进料中进行pH调节以提高EDI性能。提高RO渗透液的pH值不会改善EDI产品水质。在RO之前升高pH允许RO除去作为碳酸氢盐的CO 2,防止CO 2达到EDI。
问:EDI模块处理多少背压?
A:EDI模块上的背压仅受入口压力为100 psi或更低的要求的限制。因此,如果EDI系统以导致20psi压降的流速操作,则最大背压将为80psi。
问:EDI系统在待机后需要多长时间才能恢复质量?
答:通常,EDI系统将在从备用启动的几秒钟内恢复质量。然而,需要更长的时间,在清洁或消毒,几个小时或过夜后回到质量。
问:EDI系统的建议频率是多少?
A:消毒的频率随着客户的细菌特性而变化很大
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药徒
发表于 2016-12-20 14:14:54 | 显示全部楼层
西文 发表于 2016-12-16 09:16
本节将讨论常见问题的一些问题。如果您没有找到您的问题的答案,请联系。
问:什么是电脱离子?
A:电去 ...

厉害厉害 感谢
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发表于 2016-12-25 14:12:38 | 显示全部楼层
學到一個新知識,謝謝
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药神
发表于 2023-2-19 16:44:28 | 显示全部楼层
楼主辛苦了,感谢分享
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